
Application Note
Natural Gas Processing PlantsRegardless of the process downstream for Natural Gas Liquids extraction or Liquefied Natural Gas production, one of the first steps in a typical gas plant is acid gas (H2S and CO2) reduction and control.
Critical Control of CO2 There are a variety of H2S and CO2 reduction systems, some using liquid scrubbers such as amines or solvents, or fixed adsorbent beds, but the optimal operation of these systems requires an on-line measurement of the acid gas loading.
Traditional Measurement Solutions
On-line gas chromatographs are the traditional method widely used for monitoring the levels of CO2. However, even with the latest in chromatography techniques and dedicating a GC to only the measurement of CO2, the analysis can take 3-6 minutes between measurement updates. Due to rapid changes in the acid gas concentration, this delay may not be acceptable. Gas chromatographs consume carrier gases, so the consumable costs of GC’s are high. Non-dispersive IR Spectroscopic methods using broadband light sources and narrow band pass filters have been used but are prone to interferences from changing background concentrations.
SpectraSensors’ Solution
The SpectraSensors SS2100 offers a new solution to this control measurement. There are no cylinder gases to replace on a routine basis, so the analyzer is very low maintenance and has a low cost of ownership over the life of the analyzer. The high resolution that is inherent to TDL technology eliminates errors due to interferences that have hampered other spectrometric approaches. Tunable Diode Laser technology means that analysis is fast; results can be updated every second if desired.
Validation
The Analyzer measurement can be validated using a certified blend of CO2 in a balance that matches the typical background of the sample.
|
Component |
Minimum (Mole%) |
Normal (Mole%) |
Maximum (Mole%) |
|
Hydrogen Sulfide |
0.5 ppm |
3 – 5 ppm |
1000 ppm |
|
Water |
0.05 ppm |
<1 ppm |
10 ppm |
|
Nitrogen |
0 |
1 – 3 |
3 |
|
Oxygen |
0 |
<1 |
1 |
|
Methane |
75 |
75 - 95 |
100 |
|
Carbon Dioxide |
0.05 |
100 |
1000 |
|
Ethane |
0 |
0 - 10 |
10 |
|
Propane |
0 |
0 - 5 |
5 |
|
Butanes |
0 |
0 - 2 |
2 |
|
C5+ |
0 |
0 – 0.5 |
0.5 |
The background stream composition must be specified for proper calibration and measurement performance. Specify the Normal composition, along with the minimum and maximum expected values for each component, especially water, the measured component. Other stream compositions may be allowable with approval from SpectraSensors.
Data Sheet
Performance |
|
|
Target Components |
CO2 in Raw Natural Feed Gas |
|
Typical Measurement Ranges |
>0 – 100 ppm* (specify range) |
|
Typical Precision |
±2% of Full Scale* |
|
Measurement Response Time |
1 to ~60 sec |
|
Principle of Measurement |
Tunable Diode Laser Absorption Spectroscopy
Non-differential |
|
Environmental Temperature Range |
-20º to 50ºC (-4º to 122ºF)
-10º to 60ºC (14º to 140ºF) optional
|
|
Sample Inlet Pressure |
70 kPag (10 psig) typical
210 kPag (30 psig) maximum
|
|
Cell Temperature |
Maintain at 50ºC +/- 0.2ºC |
|
Maximum Cell Pressure |
70 kPag (10 PSIg) |
| Sample Flow Rate |
3 - 4 L/min (6.4 to 8.5 scfh)*
|
| Validation |
Certified blend of CO2 in a balance
that matches the sample
|
Electrical |
|
|
Power |
100-240 VAC, 50-60 Hz standard |
|
Max Current |
Controller: 1 A @ 120 VAC |
|
Controller to Cell Cable Length |
1m standard (3m, 5m & 10m available optionally) |
|
Communication |
Current Loop Output 4-20 mA Isolated,
1200 ohms @ 24 VDC max load
Serial: ASCII Text RS232C standard
Modbus RS232C
|
| Digital Outputs |
4 ea. 12 VDC for valve operations
Scrubber (if required), Process/Val, Val 1, Val 2
5 SPDT (Form C) Dry Contact Alarms
Common Fault, Val 1 Active, Val 2 Active, Val Fail,
one user-assignable to any alarm
|
| LCD Display |
Concentration, Cell Pressure and Temperature, Diagnostic Data |
Physical |
|
|
Controller Enclosure |
NEMA 4X - 304 Stainless Steel standard |
|
Controller Dimensions |
343mm H x 305mm W x 165mm H
(13.5" H x 12" W x 6-7/16" D)*
|
|
Weight Approximately |
13.1 Kg (28.6 lbs)* |
|
Sample Cell Dimensions |
8m Herriot Cell
559 mm H × 127 mm W (22” H × 5” W) |
|
Sample Cell Construction |
316L Series Polished Stainless Steel standard
|
| Number of Sample Cells |
1 (single channel SS2100) or
2 (dual channel SS2100)
|
| Area Classification |
CSA Certified for Class I, Division 2,
Groups ABCD Temp Code T3C
|
| Dimensions with Sample System | 1678 mm H x 613 mm W x 427 mm D (66” H x 24-1/8” W x 16-13/16” D) |
| Weight with Sample System (approx.) | 68 kg (150 lbs.) |
|
* Application specific; consult factory
|
|
Typical Accessories
|
SS2100 ARM9 Electronics
|
|
|
80000-02199 |
Temperature Control Board |
|
23000-00030 |
4-20 mA Current Loop Board
|
|
80000-02203 |
Power Supply Assembly, 120/240 VAC 50/60 Hz
|
|
80000-02300 |
Power Supply Assembly, 24 VDC
|
| 01902-17106 | External Serial Output Cable |
| 01902-30011 | Keypad Assembly |
| 24601-00002 |
Display Assembly
|
| 02203-13100 |
Daughter Board
|
| 45000-02002 |
Relay, DC12V SPDT 3 A/120 VAC
|
| Herriott Cell (8m & 28m) |
|
| 02101-17102 |
Pressure Transducer Assembly
|
| 02101-17103 |
Thermistor Assembly
|
| 02199-00006 |
Spares Kit (o-rings, fuses), AC, Viton
|
| 02199-00007 |
Cleaning Kit (domestic only)
|
